
OptMatLab group featured in the J.A. Woollam 2022 Newsletter
https://www.jawoollam.com/newsletters/issue-22
The OptMatLab research group studies the properties of matter at the nanoscale by using various spectroscopic techniques. By employing light beams with suitable characteristics, it is possible to obtain detailed information about the microscopic behavior of matter and understand its optical, electronic, chemical and structural properties. The aim of our studies is to create and advance knowledge on innovative materials and devices of relevant scientific and technological interest.
We work on several projects encompassing a wide range of materials, devices and characterization techniques. Over the years, we have built a solid competence in the determination of the optical properties of thin films (oxides, metals, polymers, DNA), bi-dimensional materials (graphene, transition metal dichalcogenides...) and nanoparticles systems. We have a suitable array of instruments that allows us to study the evolution of the materials' properties by varying the ambient conditions, such as temperature and atmosphere. The results of our work are periodically published on international peer-review journals and presesented at seminars and conferences.
The OptMatLab research group is active in the R&D of the multilayer optical coatings, which constitute the main mirrors in the Virgo gravitational wave detector (https://www.virgo-gw.eu/). Within the Einsten Telescope Infrastructure Consortium (ETIC) (https://web.infn.it/einsteintelescope/index.php/it/home-it-it/infrastrutture-e-labs/galileo), OptMatLab is developing systems for thin film deposition and characterization. These films are prototypes for the main mirrors in the Einstein Telescope, a next-generation gravitational wave detector currently under development (https://www.einstein-telescope.it/).
Instrumentation:
- Spectroscopic ellipsometer J.A. Woollam VASE (spectral range: 190-2500 nm)
- Spectroscopic ellipsometer J.A. Woollam M2000 (spectral range: 245-1700 nm)
- Spectroscopic ellipsometer SENTECH SENDIRA (spectral range: 1670-25000 nm – 6000-400 cm-1)
- Confocal Raman microscope Jasco NRS 4100
- Photothermal Common Path Interferometry (PCI) to measure ultralow optical absorption at 1550 e 1064 nm
- Optical system to measure Photoluminescence
Methods of optical spectroscopy:
- as a function of temperature, from 4 K to 900 K
- ambient atmosphere, high vacuum
- liquid ambient
Systems to grow materials in vacuum:
- Molecular Beam Epitaxy (MBE)
- Ion Beam Sputtering with in-situ ellipsometry (J.A. Woollam iSE – 400-1000 nm)
Shared instrumentation within the Dipartimento di Fisica:
- Micro-ellipsometer Park EP_4 (lateral resolution: 1 µm, spectral range: 360-1000 nm)
- X-Ray Photoemission Spectrometer with monochromatized source
People
Selected publications
Noninvasive Deterministic Nanostructures Lithography on 2D Transition Metal Dichalcogenides
Advanced Engineering Materials, 2024, 202401157.
Monitoring the evolution of optical coatings during thermal annealing with real-time, in situ spectroscopic ellipsometry
Class. Quant. Grav. 41, 2024, 175016.
Dielectric Function of 2D Tungsten Disulfide in Homo- and Heterobilayer Stacking
Advanced Materials Interfaces, 2023,10, 2201586.
(il paper è nel top 10% dei più letti sulla rivista a 12 mesi dalla pubblicazione)
Spectroscopic Ellipsometry Investigation of a Sensing Functional Interface: DNA SAMs Hybridization
Advanced Materials Interfaces, 2022, 9, 2200364.
Local Optical Properties in CVD-Grown Monolayer WS2 Flakes
J. Phys. Chem. C, 125, 16059, 2021.
Quantitative Ultrafast Electron-Temperature Dynamics in Photo-Excited Au Nanoparticles
Small, 2100050, 2021.
Optical dielectric function of two-dimensional WS2 on epitaxial graphene
2D Materials, 2020, 7, 025024.
Thermometric Calibration of the Ultrafast Relaxation Dynamics in Plasmonic Au Nanoparticles
ACS Photonics, 2020, 7, 959-966.
Plasmonics of Au/Polymer Core/Shell Nanocomposites for Thermoresponsive Hybrid Metasurfaces
ACS Applied Nano Materials, 2020, 3, 1674-1682.
Temperature-dependent permittivity of silver and implications for thermoplasmonics
Physical Review Materials, 2019, 3, 105201.
Plasmonics of Au nanoparticles in a hot thermodynamic bath
Nanoscale, 2019, 11, 1140-1146.
Anchoring of Aminophosphonates on Titanium Oxide for Biomolecular Coupling
J. Phys. Chem. C, 2019, 123, 16843-16850.
Optical properties of amorphous SiO2-TiO2 multi-nanolayered coatings for 1064-nm mirror technology
Optical Materials, 2018, 75, 94-101.
Long-lived nonthermal electron distribution in aluminum excited by femtosecond extreme ultraviolet radiation
Physical Review B, 2017, 96, 081119.